Electrochemical and Microstructural Characterization of Cr-Coated NdFeB in Neutral Wet Environment

Authors

  • V. Abanihi Department of Electrical & Electronics Engineering, Edo State University Uzairue, P.M.B. 04 Auchi, Edo State, Nigeria
  • K. K. Adama Department of Chemical Engineering, Edo State University Uzairue, P.M.B. 04 Auchi, Edo State, Nigeria.
  • I. B. Onyeachu Department of Industrial Chemistry, Edo State University Uzairue, P.M.B. 04 Auchi, Edo State, Nigeria

Keywords:

Permanent magnet, Surface Coating, Cr–oxide, Corrosion protection, EIS

Abstract

Naturally, NdFeB–based permanent magnets exhibit high chemical instability, especially, in wet environments. This makes them highly susceptible to corrosion, which leads to severe structural collapse. Applying thin surface coatings can improve the resistance to wet corrosion. In this work, 0.5 µm of chromium (Cr) film was sputtered on a sintered NdFeB–based magnet and the resistance to corrosion and microstructural damage was investigated in 3.5% NaCl solution with respect to an uncoated magnet. This was achieved by complementing potentiodynamic polarization and electrochemical impedance spectroscopy with scanning electron microscopy (SEM). The Cr coating caused a positive displacement of corrosion potential and lowered the rate of anodic dissolution. It also favored higher charge transfer resistance at the magnet–solution interface, and delivers a protection efficiency of ~ 60 %. Furthermore, grain boundary attack and deterioration were also significantly reduced by the Cr coating.

Dimensions

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Published

2023-07-24

How to Cite

Electrochemical and Microstructural Characterization of Cr-Coated NdFeB in Neutral Wet Environment. (2023). African Scientific Reports, 2(2), 102. https://doi.org/10.46481/asr.2023.2.2.102

Issue

Volume 2, Issue 2, August 2023

Section

Original Research
Copyright & Licensing

Copyright (c) 2023 V. Abanihi, K. K. Adama, I. B. Onyeachu

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

How to Cite

Electrochemical and Microstructural Characterization of Cr-Coated NdFeB in Neutral Wet Environment. (2023). African Scientific Reports, 2(2), 102. https://doi.org/10.46481/asr.2023.2.2.102